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Custom Lithium Fluoride Optical Components

Alfa Chemistry uses lithium fluoride (LiF) material for custom infrared optics. This is a colorless, crystalline substance that transmits light throughout a wide range of wavelengths, from VUV to IR, however it is most frequently employed in specialist UV optics because of its deep UV transmission. All custom LiF optics are rigorously tested by skilled experts at cutting-edge metrology facilities, giving customers the peace of mind that their needs will be met. Contact us as soon as possible to provide you with customer service!

Our Services

Alfa Chemistry provides high-quality customization of LiF parts, such as windows, lenses, and prisms, that can be manufactured in accordance with your exact requirements. We can provide both coated and uncoated optical options, including Broadband Translucency Augmentation (BBAR) coatings. The table below lists our typical manufacturing requirements. If your needs are not covered by the aforementioned list, get in touch with our technical sales team. We can help you since we have a lot of experience in this area.

Advantages and Uses of Custom Lithium Fluoride Optical Components

LiF Windows

Diameter Range5 mm ~ 60 mm
Diameter Tolerance± 0.1 mm
Centre Thicknessup to 30 mm
Centre Thickness Tolerance± 0.05 mm
Clear Aperture90%
Centration Tolerance1 arc minute
Form Errorbetter than λ/4 (633nm) over aperture
Surface Radius Tolerance1 fringe over aperture
Linear Dimensionup to 60 mm
Linear Tolerance± 0.1 mm
Angular Tolerance5 arc minutes
Edge Finishground
Chamfer0.3x0.3@45°
Surface Quality20-10 scratch/ dig

LiF Prisms

Length of Hypotenuseup-to 60 ± 0.1 mm
Length of Sidesup-to 60 ± 0.1 mm
Thickness30 ± 0.05 mm
Angle Tolerancebetter than 1 arc minute
Edge Finishground, blacked
Clear Aperture90% of entrance dimensions
Chamfer0.3x0.3@45°
Form Error0.2 fringe from test flat
Surface Quality20-10 scratch/dig

LiF Ground Blanks

Diameter Rangeless than 5 mm to 60 mm
Diameter Tolerancebetter than ± 0.5 mm
Centre Thicknessup to 30 mm
Centre Thickness Tolerancebetter than ± 0.5 mm
Clear Aperture90%
Linear Dimensionup to 60 mm
Linear Tolerancebetter than ± 0.5 mm
Angular Tolerancebetter than 10 arc minutes
Edge Finishfine ground N6
Chamfer0.3x0.3@45°

Applications:

  • X-ray Monochromator Plates: Due to a certain lattice gap, the LiF crystal structure reflects X-rays at a particular wavelength and incidence angle. This process is called Bragg diffraction. Monochromatic X-ray beams can be chosen using LiF plates.
  • Transmission Windows: LiF windows are frequently employed in VUV and excimer lasers due to their excellent VUV transmission.

LiF's Optical Properties

LiF is frequently used to create windows, prisms, and lenses in the vacuum UV, ultraviolet, visible, and infrared spectrums due to its high transmittance. Out of the frequently used infrared materials, LiF has the lowest refractive index. Additionally, at 121 nm, it transmits above the hydrogen Lyman-alpha line, giving it the highest UV transmittance of any IR material.

LiF can be utilized up to 600°C in dry conditions even though it is highly insoluble in water and is destroyed by ambient moisture at about 400°C. LiF is susceptible to thermal shocks brought on by abrupt temperature fluctuations, which can cause the material to break.

Color online Structure of a LiF crystal.Fig 1. Color online Structure of a LiF crystal. (Buth C, et al. 2005)

Below is a quick description of LiF's optical characteristics. For more information on the properties of LiF materials please click here.

Transmission Range0.12 to 6 µm
Refractive Index1.392@0.6 µm
Melting Point848 °C
Density2.639 g/cm3
HardnessKnoop 102 with 600g indenter

If you need technical advice, please contact our technical team to learn more about our high-quality services.

Reference

  1. Buth C, et al. (2005). "Ab Initio Green's Function Formalism for Band Structures." Physical Review. B, Condensed Matter. 72(19):195107.

Please kindly note that our products and services are for research use only.